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In which of the following would the bonding be strengthened with the addition of an electron to form the negative molecular ion


A) N2
B) O2
C) F2
D) all of these
E) none of these

F) C) and D)
G) B) and C)

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Which of the following molecules has polar bonds but is a nonpolar molecule PCl5, PCl3, NCl3, CO2


A) NCl3 and CO2
B) PCl5 and CO2
C) PCl3 and CO2
D) PCl5, PCl3, NCl3 and CO2
E) None of the above

F) D) and E)
G) B) and E)

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The hybridization of B in the BF3 molecule is sp3.

A) True
B) False

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N,N-diethyl-m-tolumide (DEET) is the active ingredient in many mosquito repellents. What is the hybridization state of carbon indicated by the arrow in the structure of DEET shown below N,N-diethyl-m-tolumide (DEET)  is the active ingredient in many mosquito repellents. What is the hybridization state of carbon indicated by the arrow in the structure of DEET shown below    A)  sp B)  sp<sup>2</sup> C)  sp<sup>3</sup> D)  sp<sup>3</sup>d E)  sp<sup>3</sup>d<sup>2</sup>


A) sp
B) sp2
C) sp3
D) sp3d
E) sp3d2

F) B) and D)
G) None of the above

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Indicate the type of hybrid orbitals used by the central atom in BrF3.


A) sp
B) sp2
C) sp3
D) sp3d
E) sp3d2

F) B) and C)
G) A) and C)

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The hybridization of the central nitrogen atom in the molecule N2O is


A) sp.
B) sp2.
C) sp3.
D) sp3d.
E) sp3d2.

F) C) and E)
G) A) and B)

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The number of pi bonds in the oxalate ion (C2O42-) is


A) 1
B) 2
C) 3
D) 4
E) 5

F) B) and D)
G) B) and C)

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In VSEPR theory the molecular geometry of SF4 (sulfur tetrafluoride) is distorted tetrahedron (seesaw).

A) True
B) False

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The geometry of the hybrid orbitals about a central atom with sp3d hybridization is:


A) linear
B) trigonal planar
C) tetrahedral
D) bent
E) trigonal bipyramidal

F) B) and E)
G) C) and D)

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A central atom with 4 electron pairs (single bonds and/or lone pairs of electrons) could have which of the following molecular geometries I. Trigonal bipyramidal II. Tetrahed ral III. Trigonal pyramidal IV. Bent


A) I and II
B) II and III
C) II, III, and IV
D) I and IV
E) I, II, and IV

F) D) and E)
G) A) and E)

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Indicate the type of hybrid orbitals used by the central atom in PCl3.


A) sp
B) sp2
C) sp3
D) sp3d
E) sp3d2

F) A) and B)
G) B) and D)

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The bond in O2 is shorter than the bond in O2+.

A) True
B) False

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The geometry of the hybrid orbitals of the central atom of a molecule is always the same as molecular geometry.

A) True
B) False

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More energy is required to break a bond with an order of 3/2 than is required to break a bond of order 2.

A) True
B) False

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A central atom with 5 electron pairs (single bonds and/or lone pairs of electrons) could have which of the following molecular geometries I. Trigonal bipyramidal II. Seesaw III. T-shaped IV. Linear


A) I, II, and III
B) II, III, and IV
C) I, III, and IV
D) I, II, and IV
E) I, II, III, and IV

F) D) and E)
G) A) and E)

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Give the number of lone pairs around the central atom and the molecular geometry of SCl2.


A) 0 lone pairs, linear
B) 1 lone pair, bent
C) 2 lone pairs, bent
D) 3 lone pairs, bent
E) 3 lone pairs, linear

F) D) and E)
G) All of the above

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N,N-diethyl-m-tolumide (DEET) is the active ingredient in many mosquito repellents. What is the hybridization state of the nitrogen atom in the structure of DEET shown below N,N-diethyl-m-tolumide (DEET)  is the active ingredient in many mosquito repellents. What is the hybridization state of the nitrogen atom in the structure of DEET shown below   A)  sp B)  sp<sup>2</sup> C)  sp<sup>3</sup> D)  sp<sup>3</sup>d E)  sp<sup>3</sup>d<sup>2</sup>


A) sp
B) sp2
C) sp3
D) sp3d
E) sp3d2

F) None of the above
G) A) and E)

Correct Answer

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What is the bond order of CO+


A) 1
B) 1.5
C) 2
D) 2.5
E) 3

F) D) and E)
G) C) and D)

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Indicate the type of hybrid orbitals used by the central atom in SF6.


A) sp
B) sp2
C) sp3
D) sp3d
E) sp3d2

F) B) and E)
G) C) and E)

Correct Answer

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A sp2 hybridized central atom has what angles between its hybrid orbitals


A) 145 \circ
B) 120 \circ
C) 109.5 \circ
D) 90 \circ
E) < 90 \circ

F) D) and E)
G) A) and E)

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