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The normal process occurring on Earth that warms its surface and the lower atmosphere is called


A) photosynthesis.
B) vaporization of water.
C) incomplete combustion.
D) the greenhouse effect.
E) the ozone hole.

F) C) and D)
G) B) and D)

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What mass of solid CaO is needed to remove the sulfur dioxide from 1.0 × 106 m3 of air having an SO2 concentration of 1.5 × 10-9 M? Assume that the reaction leading to removal of the sulfur dioxide is CaO(s) + SO2(g) \rarr CaCO3(s) .


A) 56 g
B) 96 g
C) 37 g
D) 84 g
E) 43 g

F) B) and D)
G) All of the above

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Which of the following would NOT help reduce the amount of CO2 introduced into the atmosphere?


A) Improving energy efficiency in automobiles
B) Use of nuclear energy
C) Recover methane gas generated at landfills
D) Preservation of the Amazon jungle
E) Converting forests to farmland for crops and grassland for cattle

F) All of the above
G) None of the above

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The most prevalent noble gas in our atmosphere is


A) helium.
B) neon.
C) argon.
D) krypton.
E) xenon.

F) A) and B)
G) D) and E)

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Determine two effects expected from the depletion of the ozone layer. 1) asthma 2) lung cancer 3) skin cancer 4) genetic mutations 5) emphysema


A) 1 and 5
B) 2 and 3
C) 3 and 5
D) 3 and 4
E) 4 and 5

F) D) and E)
G) B) and D)

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What happens to nitrogen dioxide in sunlight? Write the reaction for this process.

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It decompo...

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Peroxyacetyl nitrate, called PAN for short, is a powerful lachrymator.A lachrymator is


A) a greenhouse gas.
B) a product of incomplete combustion.
C) an agent that induces drowsiness.
D) a cancer causing agent.
E) a tear producer.

F) B) and E)
G) A) and C)

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Write out the steps in the reaction scheme for nitrogen fixation by lightening.

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N2(g)+ O2(g) blured image 2NO(g)
2...

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List the following greenhouse gases in order of their overall magnitude of contribution to global warming: N2O, CFCs, CO2, CH4


A) N2O < CFCs < CO2 < CH4
B) N2O < CH4 < CFCs < CO2
C) CO2 < N2O < CFCs < CH4
D) CH4 < CFCs < N2O < CO2
E) N2O < CFCs < CH4 < CO2

F) C) and D)
G) B) and E)

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The compound CFCl3 is used as a/an


A) enzyme
B) anesthetic
C) gaseous fuel
D) coolant
E) CFC replacement

F) A) and C)
G) A) and D)

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One of the steps in the fixation of nitrogen by lightening is given below. 2NO2(g) + H2O(l) \rarr HNO2(aq) + HNO3(aq) In this reaction, is the element nitrogen oxidized or reduced?


A) Nitrogen is oxidized in this reaction.
B) Nitrogen is reduced in this reaction.
C) Nitrogen is oxidized and reduced in this reaction.
D) Nitrogen is neither oxidized nor reduced in this reaction.

E) B) and C)
F) All of the above

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The first "hole" in the ozone layer was found over which continent?


A) North America
B) South America
C) Australia
D) Antarctica
E) Asia

F) C) and D)
G) A) and C)

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D

Which region of the atmosphere contains the ozone layer?


A) thermosphere
B) mesosphere
C) stratosphere
D) troposphere

E) A) and C)
F) All of the above

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Select all of the following that are capable of destroying stratospheric ozone through chemical meAns : I.CF2Cl2 II.NO III.CO2


A) I, II, and III
B) I and III
C) II and III
D) I and II
E) I only

F) All of the above
G) C) and E)

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D

Write out the steps in the mechanism by which ozone is formed in the stratosphere.

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O2(g)+ hblured image 2O...

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An unusual atmospheric reaction leading to ozone destruction is CF3O + O3 \rarr CF3O2 + O2, the analysis of which has yielded an Arrhenius frequency factor (A) and activation energy of 2.0 × 10-12 cm3 molecule-1 s-1 and 11.6 kJ/mol, respectively.Calculate the rate constant for this reaction at an altitude of 35 km, where the temperature is -34°C.


A) 2.0 × 10-12 M-1 s-1
B) 1.2 × 109 M-1 s-1
C) 3.5 × 106 M-1 s-1
D) 7.9 × 10-15 M-1 s-1
E) 6.8 × 108 M-1 s-1

F) D) and E)
G) A) and D)

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A possible reaction leading to removal of ClO from the atmosphere is 2ClO \rarr Cl2 + O2.Studies of this reaction have yielded an Arrhenius frequency factor, A, and an activation energy of 1.0 × 10-12 cm3 molecule-1 s-1 and 13.2 kJ/mol, respectively.Calculate the rate constant for the disappearance of ClO at -30°C.


A) 1.5 × 10-15 M-1 s-1
B) 8.7 × 105 M-1 s-1
C) 2.9 × 10-15 M-1 s-1
D) 9.9 × 10-13 M-1 s-1
E) 1.7 × 106 M-1 s-1

F) A) and B)
G) A) and E)

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E

Write out the steps in the mechanism of ozone destruction by nitric oxide (NO).

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NO(g)+ O3(g...

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The rate constant of the reaction Cl + CHCl3 \rarr HCl + CCl3 is 5.8 × 107 M-1s-1 at 25°C and has an activation energy of 11.0 kJ/mol.Calculate the rate constant for this reaction in the lower stratosphere where the temperature is -57°C.


A) 1.1 × 107 M-1 s-1
B) 4.2 × 107 M-1 s-1
C) 4.9 × 109 M-1 s-1
D) 9.5 × 106 M-1 s-1
E) 2.7 × 109 M-1 s-1

F) B) and C)
G) C) and D)

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Determine which of the following pollutants are of capable of forming acid rain when combined with water. I.SO2 II.SO3 III.CaCO3 IV.CaO


A) I and II
B) III and IV
C) I, II, III, and IV
D) II and III
E) I, II and IV

F) A) and D)
G) B) and D)

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