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The scattering of helium atoms by a solid can be used to gain information about the lattice of atoms, provided the wavelength of the helium atoms is comparable to the dimensions of the lattice.What is the wavelength, in picometers, of a helium-4 atom with a kinetic energy of 0.10 eV.(mass of 4He = 4.0026 amu; 1 amu = 1.67 * 10-24 g; 1 eV = 1.602 * 10-19 J; h = 6.626 * 10-34 J.s)

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Calculate the frequency of the light emitted by a hydrogen atom during a transition of its electron from the n = 4 to the n = 1 principal energy level. Recall that for hydrogen En = -2.18 *10 -18 J(1/n2)


A) 3.08 * 1015 /s
B) 1.03 * 108 /s
C) 2.06 * 1014 /s
D) 1.35 * 10-51 /s
E) 8.22 * 1014 /s

F) A) and B)
G) C) and D)

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What is the wavelength, in meters, of an alpha particle with a kinetic energy of 8.0 * 10-13 J.(mass of an alpha particle = 4.00150 amu; 1 amu = 1.67 * 10-27 kg)

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6.4 * 10

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What is the energy in joules of one photon of microwave radiation with a wavelength 0.122 m? (c = 2.9979 * 108 m/s; h = 6.626 * 10-34 J0s)


A) 2.70 * 10-43 J
B) 5.43 * 10-33 J
C) 1.63 * 10-24 J
D) 4.07 * 10-10 J
E) 2.46 * 109 J

F) B) and C)
G) B) and E)

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Which one of the following sets of quantum numbers is not possible? Which one of the following sets of quantum numbers is not possible?

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Calculate the frequency of visible light having a wavelength of 686 nm.


A) 4.37 * 1014 /s
B) 4.37 * 105 /s
C) 6.17 * 1014 /s
D) 2.29 * 10-15 /s
E) 2.29 * 10-6 /s

F) C) and E)
G) A) and D)

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If a hydrogen atom and a helium atom have the same kinetic energy,


A) the wavelength of the hydrogen atom will be about 4 times longer than the wavelength of the helium atom.
B) the wavelength of the hydrogen atom will be about 2 times longer than the wavelength of the helium.
C) the wavelength of the hydrogen atom will be roughly equal to the wavelength of the helium atom.
D) the wavelength of the helium atom will be about 2 times longer than the wavelength of the hydrogen atom.
E) the wavelength of the helium atom will be about 4 times longer than the wavelength of the hydrogen atom.

F) A) and B)
G) A) and C)

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How many electrons in a ground-state tellurium atom are in orbitals labeled by l = 1?


A) 4
B) 10
C) 12
D) 16
E) 22

F) B) and D)
G) A) and E)

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What is the wavelength of radiation that has a frequency of 2.10 *1014 s -1?


A) 6.30 * 1022 m
B) 7.00 * 102 nm
C) 7.00 * 105 m
D) 1.43 * 10-6 m
E) 3.00 * 108 m

F) A) and B)
G) A) and E)

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A ground-state atom of manganese has ___ unpaired electrons and is _____.


A) 0, diamagnetic
B) 2, diamagnetic
C) 3, paramagnetic
D) 5, paramagnetic
E) 7, paramagnetic

F) B) and E)
G) A) and B)

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The ground-state electron configuration for an atom of indium is


A) [Kr]5s24p64d5
B) [Ar]4s23d104p1
C) [Ar]4s24p63d5
D) [Kr]5s25p64d5
E) [Kr]5s24d105p1

F) B) and C)
G) B) and E)

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How many orbitals are allowed in a subshell if the angular momentum quantum number for electrons in that subshell is 3?


A) 1
B) 3
C) 5
D) 7
E) 9

F) B) and E)
G) D) and E)

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The bonds of oxygen molecules are broken by sunlight.The minimum energy required to break the oxygen-oxygen bond is 495 kJ/mol. What is the wavelength of sunlight that can cause this bond breakage?

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The electron in a hydrogen atom falls from an excited energy level to the ground state in two steps, causing the emission of photons with wavelengths of 2624 and 97.2 nm. What is the quantum number of the initial excited energy level from which the electron falls?


A) 2
B) 3
C) 4
D) 6
E) 8

F) A) and E)
G) B) and C)

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A neon atom in its ground state will be diamagnetic.

A) True
B) False

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Which of the following is the electron configuration of an excited state of an iron atom?


A) [Ar]4s23d7
B) [Ar]4s23d6
C) [Ar]4s23d8
D) [Ar]4s13d7
E) [Ar]4s13d5

F) A) and B)
G) A) and C)

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If we take away two electrons from the outer shell of calcium, it would have the same electron configuration as what element?

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The electron configuration of a ground-state vanadium atom is


A) [Ar]4s24d3
B) [Ar]4s24p3
C) [Ar]4s23d3
D) [Ar]3d5

E) A) and B)
F) A) and C)

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Breaking the oxygen-oxygen bond in hydrogen peroxide requires 210 kJ/mol. What is the longest wavelength of light that can cause this bond to be broken?


A) 5.7 * 10-4 m
B) 9.5 * 10-31 m
C) 2.8 * 10-7 m
D) 9.5 * 10-28 m
E) 5.7 * 10-7 m

F) A) and D)
G) None of the above

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Calculate the wavelength of a neutron that has a velocity of 250 cm/s. (The mass of a neutron = 1.675 * 10-24 g; h = 6.626 * 10-34 J.s)


A) 16 pm
B) 0.016 nm
C) 0.16 nm
D) 160 nm
E) 1.6 * 10-4 m

F) A) and B)
G) A) and C)

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