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Calculate the pH of a 0.040 M perchloric acid (HClO4) solution.


A) 1.40
B) 2.10
C) 12.60
D) 11.90
E) none of these

F) A) and C)
G) B) and E)

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Calculate [H+] in a 1.2 10-5 M solution of NH4Cl. (Kb for NH3 = 1.8 10-5)


A) 1.5 10-5 M
B) 8.2 10-8 M
C) 1.3 10-7 M
D) 1.2 10-5 M
E) 7.7 10-8 M

F) A) and C)
G) D) and E)

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Calculate [H+] in a 0.012 M solution of HCN, Ka = 6.2 10-10.


A) 3.0 10-7 M
B) 3.7 10-9 M
C) 6.2 10-10 M
D) 2.7 10-6 M
E) 2.3 10-4 M

F) B) and E)
G) A) and E)

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Which of the following species is not amphoteric?


A) H2PO4-
B) HPO42-
C) H2O
D) HSO4-
E) All of these are amphoteric.

F) A) and B)
G) B) and C)

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Which of the following reactions is associated with the definition of Ka?


A) [Al(OH2) 6]3+
Which of the following reactions is associated with the definition of K<sub>a</sub>? A)  [Al(OH<sub>2</sub>) <sub>6</sub>]<sup>3+ </sup> <sup> </sup>   Al(OH) (OH<sub>2</sub>) <sub>5</sub><sup>2+</sup> + H<sup>+</sup> B)  CN<sup>-</sup> + H<sup>+</sup>   HCN C)  OCl<sup>-</sup> + H<sub>2</sub>O   HOCl + OH<sup>-</sup> D)  Al<sup>3+</sup> + 6H<sub>2</sub>O   Al(OH<sub>2</sub>) <sub>6</sub><sup>3+</sup> Al(OH) (OH2) 52+ + H+
B) CN- + H+ Which of the following reactions is associated with the definition of K<sub>a</sub>? A)  [Al(OH<sub>2</sub>) <sub>6</sub>]<sup>3+ </sup> <sup> </sup>   Al(OH) (OH<sub>2</sub>) <sub>5</sub><sup>2+</sup> + H<sup>+</sup> B)  CN<sup>-</sup> + H<sup>+</sup>   HCN C)  OCl<sup>-</sup> + H<sub>2</sub>O   HOCl + OH<sup>-</sup> D)  Al<sup>3+</sup> + 6H<sub>2</sub>O   Al(OH<sub>2</sub>) <sub>6</sub><sup>3+</sup> HCN
C) OCl- + H2O Which of the following reactions is associated with the definition of K<sub>a</sub>? A)  [Al(OH<sub>2</sub>) <sub>6</sub>]<sup>3+ </sup> <sup> </sup>   Al(OH) (OH<sub>2</sub>) <sub>5</sub><sup>2+</sup> + H<sup>+</sup> B)  CN<sup>-</sup> + H<sup>+</sup>   HCN C)  OCl<sup>-</sup> + H<sub>2</sub>O   HOCl + OH<sup>-</sup> D)  Al<sup>3+</sup> + 6H<sub>2</sub>O   Al(OH<sub>2</sub>) <sub>6</sub><sup>3+</sup> HOCl + OH-
D) Al3+ + 6H2O Which of the following reactions is associated with the definition of K<sub>a</sub>? A)  [Al(OH<sub>2</sub>) <sub>6</sub>]<sup>3+ </sup> <sup> </sup>   Al(OH) (OH<sub>2</sub>) <sub>5</sub><sup>2+</sup> + H<sup>+</sup> B)  CN<sup>-</sup> + H<sup>+</sup>   HCN C)  OCl<sup>-</sup> + H<sub>2</sub>O   HOCl + OH<sup>-</sup> D)  Al<sup>3+</sup> + 6H<sub>2</sub>O   Al(OH<sub>2</sub>) <sub>6</sub><sup>3+</sup> Al(OH2) 63+

E) All of the above
F) C) and D)

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Calculate the pH of a 0.005 M solution of potassium oxide, K2O.


A) 2.3
B) 11.7
C) 7.0
D) 12.0
E) 2.0

F) A) and E)
G) A) and B)

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If the following substance is dissolved in pure water, will the solution be acidic, neutral, or basic? solid sodium bicarbonate (NaHCO3)


A) basic
B) neutral
C) acidic

D) All of the above
E) B) and C)

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Arrange the following 0.10 M solutions from lowest to highest pH: NaF, NaC2H3O2, C5H5NHCl, KOH, HCN. (Ka for HCN is 6.2 10-10; Ka for HF is 7.2 10-4; Ka for HC2H3O2 is 1.8 10-5; and Kb for C5H5N is 1.7 10-9)


A) C5H5NHCl, HCN, NaF, NaC2H3O2, KOH
B) NaF, NaC2H3O2, HCN, C5H5NHCl, KOH
C) KOH, NaC2H3O2, NaF, HCN, C5H5NHCl
D) HCN, C5H5NHCl, NaF, NaC2H3O2, KOH
E) none of these

F) C) and E)
G) D) and E)

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The following three equations represent equilibria that lie far to the right. HNO3(aq) + CN-(aq) The following three equations represent equilibria that lie far to the right. HNO<sub>3</sub>(aq)  + CN<sup>-</sup>(aq)    HCN(aq)  + NO<sub>3</sub><sup>-</sup>(aq)  HCN(aq)  + OH<sup>-</sup>(aq)    H<sub>2</sub>O(l)  + CN<sup>-</sup>(aq)  H<sub>2</sub>O(l)  + CH<sub>3</sub>O<sup>-</sup>(aq)    CH<sub>3</sub>OH(aq)  + OH<sup>-</sup>(aq)  -Identify the strongest base. A)  CH<sub>3</sub>OH B)  CH<sub>3</sub>O<sup>-</sup> C)  H<sub>2</sub>O D)  NO<sub>3</sub><sup>-</sup> E)  CN<sup>-</sup> HCN(aq) + NO3-(aq) HCN(aq) + OH-(aq) The following three equations represent equilibria that lie far to the right. HNO<sub>3</sub>(aq)  + CN<sup>-</sup>(aq)    HCN(aq)  + NO<sub>3</sub><sup>-</sup>(aq)  HCN(aq)  + OH<sup>-</sup>(aq)    H<sub>2</sub>O(l)  + CN<sup>-</sup>(aq)  H<sub>2</sub>O(l)  + CH<sub>3</sub>O<sup>-</sup>(aq)    CH<sub>3</sub>OH(aq)  + OH<sup>-</sup>(aq)  -Identify the strongest base. A)  CH<sub>3</sub>OH B)  CH<sub>3</sub>O<sup>-</sup> C)  H<sub>2</sub>O D)  NO<sub>3</sub><sup>-</sup> E)  CN<sup>-</sup> H2O(l) + CN-(aq) H2O(l) + CH3O-(aq) The following three equations represent equilibria that lie far to the right. HNO<sub>3</sub>(aq)  + CN<sup>-</sup>(aq)    HCN(aq)  + NO<sub>3</sub><sup>-</sup>(aq)  HCN(aq)  + OH<sup>-</sup>(aq)    H<sub>2</sub>O(l)  + CN<sup>-</sup>(aq)  H<sub>2</sub>O(l)  + CH<sub>3</sub>O<sup>-</sup>(aq)    CH<sub>3</sub>OH(aq)  + OH<sup>-</sup>(aq)  -Identify the strongest base. A)  CH<sub>3</sub>OH B)  CH<sub>3</sub>O<sup>-</sup> C)  H<sub>2</sub>O D)  NO<sub>3</sub><sup>-</sup> E)  CN<sup>-</sup> CH3OH(aq) + OH-(aq) -Identify the strongest base.


A) CH3OH
B) CH3O-
C) H2O
D) NO3-
E) CN-

F) A) and D)
G) A) and E)

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How much water should be added to 10.0 mL of 12.0 M HCl so that it has the same pH as 0.90 M acetic acid (Ka = 1.8 10-5) ? (Assume the volumes are additive.)


A) 30 mL
B) 3 L
C) 30 L
D) 300 L
E) 300 mL

F) A) and D)
G) C) and D)

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For the equilibrium that exists in an aqueous solution of nitrous acid (HNO2, a weak acid) , the equilibrium constant expression is


A) For the equilibrium that exists in an aqueous solution of nitrous acid (HNO<sub>2</sub>, a weak acid) , the equilibrium constant expression is A)    B)    C)    D)  K = [H<sup>+</sup>][NO<sub>2</sub><sup>-</sup>] E)  none of these
B) For the equilibrium that exists in an aqueous solution of nitrous acid (HNO<sub>2</sub>, a weak acid) , the equilibrium constant expression is A)    B)    C)    D)  K = [H<sup>+</sup>][NO<sub>2</sub><sup>-</sup>] E)  none of these
C) For the equilibrium that exists in an aqueous solution of nitrous acid (HNO<sub>2</sub>, a weak acid) , the equilibrium constant expression is A)    B)    C)    D)  K = [H<sup>+</sup>][NO<sub>2</sub><sup>-</sup>] E)  none of these
D) K = [H+][NO2-]
E) none of these

F) A) and E)
G) All of the above

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The pH of a strong acid solution is always lower than the pH of a weak acid solution. If this is true, explain why and include an example with calculations. If it is false, explain why and include a counterexample with calculations.

A) True
B) False

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If the following substance is dissolved in pure water, will the solution be acidic, neutral, or basic? solid ammonium fluoride (NH4F) For NH3, Kb = 1.8 10-5; for HF, Ka = 7.2 10-4.


A) neutral
B) basic
C) acidic

D) B) and C)
E) All of the above

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HOAc Ka = 1.8 10-5 H2CO3 Ka1 = 4.3 10-7, Ka2 = 5.6 10-11 Which of the following 0.01 M solutions has the highest pH?


A) HOAc
B) NaHCO3
C) H2CO3
D) NaOAc
E) Na2CO3

F) A) and B)
G) None of the above

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Calculate the pOH of a 0.70 M solution of acetic acid (Ka = 1.8 10-5) at 25°C.


A) 2.72
B) 9.26
C) 4.90
D) 11.55
E) 2.45

F) A) and C)
G) A) and B)

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The conjugate base of a weak acid is


A) a strong base.
B) a strong acid.
C) a weak base.
D) a weak acid.
E) none of these

F) A) and E)
G) None of the above

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The pH of a solution made of 0.100 mol of a weak monoprotic acid HA in 1.000 L of solution is 1.470. Calculate Ka for this acid.


A) 29.5
B) 0
C) 0.100
D) 0.0174
E) 0.0339

F) None of the above
G) B) and D)

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If the following substance is dissolved in pure water, will the solution be acidic, neutral, or basic? solid sodium cyanide (NaCN)


A) neutral
B) basic
C) acidic

D) A) and B)
E) All of the above

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Calculate the pH of a 2.0 10-5 M solution of HOC6H5. (Ka = 1.6 10-10)


A) 6.94
B) 6.75
C) 7.06
D) 7.25
E) none of these

F) A) and D)
G) C) and D)

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